A Comparison of Hard Water, Softened Water

and Reverse Osmosis Water

By: Leanne S.



 

TABLE OF CONTENTS

ABSTRACT
PURPOSE
HYPOTHESIS
EXPERIMENT DESIGN
MATERIALS
PROCEDURES
BACKGROUND REPORT
RESULTS
ANALYSIS AND CONCLUSIONS
BIBLIOGRAPHY
APPENDIX

 

ABSTRACT

I did a few different experiments to find the differences of Hard Water, Softened Water and Reverse Osmosis Water.  The first test was to see how much metal the different water types contained.  The second test was to see how much soap is left in clothes after washing them.  The third test was to see the effects of soap on each water type.  I hoped to learn what water type is best. 

For each test I figured (because all the research I did) that the Hard Water would be the worst, the Soft Water would be second best and RO Water would be the best. 

For the first experiment I took readings from a TDS meter. For the second I washed three washcloths with soap and rinsed each with a different kind of water, then filled each container with 2 quarts RO Water and shook each for a minute.  For the third test I took three glass jars, filled with different water types then put soap in each and shook. 

I found that hard water should not be used.  It doesn't work well with soap and it has a high amount of minerals.  Softened water works well with soap and RO Water had the best results for each experiment.
 


PURPOSE


 


Test #1
The purpose of this experiment is to measure the conductivity of the different types of water. I wanted to solve this problem so I would know how much metal the water contains. This can help people by letting them know how much metal is in their water for health issues, and cleaning. 

Test #2
The purpose of this experiment is to see which kind of water rinses out the most amount of soap from clothing fabrics.  This will help everyone who wears and washes clothes.  The experiment can help us learn what kind of water we would want to wash our clothes in.  The water we would want to choose is the one that rinses out the most amount of soap.  The least amount of soap is the best because it shows that most of the soap has been rinsed out.  You don’t want soap in your clothes because soap causes skin irritation and the colors in your clothes to fade quicker than usual. 

Test #3
The purpose of this experiment is to find the effects of minerals in water on soap. I wanted to solve this problem so I know what kind of water is best to use to rinse soap out of clothes, off dishes etc. This can help people by letting them know that a certain kind of water is better to use to reduce amounts of soap in clothes and raise the efficiency of rinsing soap off of used objects.
 


HYPOTHESIS


 






Test #1
My hypothesis is that hard water will contain more metal parts per million. Secondly softened water will have some but not tremendous amounts of metal. RO water will have a very low count of metal parts per million. I arrived at this hypothesis because I found that hard water contains a lot of minerals. I have also found that softeners are used to reduce great amounts of minerals. Finally I found that Reverse Osmosis reduces about 99% of the minerals that the water contains. 

Test #2
My hypothesis is that the hard water will have quite a few suds, I think that the bubbles will be at an average of about 5 millimeters.  The softened water will have a very small amount of soap left. The softened water will have about a millimeter of soap. Finally I don’t think there will be any soap with the RO water. I have arrived at this hypothesis because I have read that hard water does not rinse out very much of the soap that it has been washed in. Instead of rinsing the soap out it causes it to form a paste and it sticks to the cloth. I have also read that soft water has a reduced amount of minerals so as a result the paste will not form and sick to the cloth. The RO water has almost 99% of the minerals removed so it won’t make even the slightest bit of paste, so the soap will not stick to the cloth. 

Test #3
My hypothesis for this experiment is that RO water will have the most amount of bubbles from one drop of soap, while softened water will have the second highest amounts of bubbles and hard water will have very few bubbles if any at all. I have come to this hypothesis from the research I did that involved soap. When the fats in the soap mixes with the minerals in the water precipitation occurs. When the calcium and magnesium ions form insoluble salts with the fat in the soap, a curd-like precipitate occurs and settle. So as a result the soap is mixed with the water minerals and is not able to make bubbles like it is supposed to. The hard water has the most amount of minerals so it should not have very many bubbles, while the softened water has very little amounts of minerals, so it is aloud to form more bubbles. The RO water should have the most amount of bubbles because 99% of the minerals have been taken out so the soap doesn’t have to compete with as many minerals as the other two.

EXPERIMENT DESIGN 

In my project the manipulated variables are the three different types of water, Hard water, Soft water and Reverse Osmosis water. The Responding variables in test number one were how much conductivity was in each water type. Each were measured by parts per million. In test number two the responding variables were how many millimeters high the bubbles were from the soap that was left in each cloth. In my final test (number three) the responding variables were again how high the bubbles were in millimeters. In this test it showed how well the bubbles formed with each water type.

The control groups in test number one and test number three were tap water because the water is natural and not processed. In the second test the control group was Reverse Osmosis water because it was the most processed water and has the least amount of minerals. You would want the water with the least amount of minerals so that the soap would not stick to the minerals and cause the soap in the cloth not to form bubbles.

Test #1

·Same amounts of water


·Same TDS meter

·Same water source for each type

·Same length of time in water

·Glass used must be clean

Test #2

·Same type of cloth
·Same size cloths
·Same amounts of water for each step
·Same amount of time for each cleaning, rinsing and shaking time

·Measure amount of bubbles directly after shaking

·Water from the same source for each type

·Same amounts of soap

·Measure from the surface of the water to the top of the bubbles

·Water temperature must all be the same

Test #3

·Same amount of soap


·Same amount of water 

·Water comes from same source for each type

·Shake for the same amount of time

·Measure from the surface of the water to the top of the bubbles

·Water temperature must be the same

My first experiment I measured the conductivity in each water type by parts per million. In my second test I measured the amount of suds left from each piece of cloth in millimeters, from the surface of the water to the top of the bubbles. My final test (3rd) I again measured the amount of suds, the difference is that it showed how well the soap interacted with each water type. I measured the bubbles from the surface of the water to the top of the bubbles in millimeters.
 


MATERIALS

Test #1 


TDS meter 
Eight-ounce glasses 
RO water 
Hard water 
Softened water



2 oz 
2 oz 
2 oz

 
Test #2 


Wash Cloths 
Liquid Soap (.75ml) 
1 gallon containers (clear, with tight lids) 
Hard Water 
Softened Water 
RO Water 
Clothes Dryer 
Timer 
Metric Ruler 



3  (.25mL for each rag) 


2 quarts 
2 quarts 
5 quarts 


1


 

Test #3

Liquid Soap (.75ml) 
Glass Bottles (clear, with lids) 
RO Water 
Hard Water 
Soft Water 
Metric Ruler 3 (.25 for each bottle)
 

3

3
100ml
100ml
100ml


1
 

PROCEDURES


 


Test #1
1. Fill glass with enough hard water to reach the line on the TDS meter.
2. Fill a second glass with RO water (to reach line).
3. Fill a third glass with softened water, also to reach the line.
4. Put TDS meter in glass 1.
5. Push button to turn on.
6. Keep in water for about one minute.
7. Clean meter with RO water.
8. Put meter in glass 2.
9. Let sit for a minute.
10. Clean meter.
11. Put probe in glass 3.
12. Put in water for one minute. 

Test #2
1. Cloth #1, wash with soap and 1 quart hard water.
2. Rinse container with hard water.
3. Rinse Cloth #1 in 1 quart hard water.
4. Dry.
5. Cloth #2, wash with soap and 1 quart softened water.
6. Rinse container with soft water.
7. Rinse cloth with 1 quart soft water.
8. Dry.
9. Cloth #3, wash with soap and 1 quart RO water.
10. Rinse container with RO water.
11. Rinse cloth with 1 quart RO water.
12. Dry.
13. Fill gallon container #1 with 1 quart RO water.
14. Fill container #2 with 1 quart RO water.
15. Fill container #3 with 1 quart RO water.
16. Shake each for 30 seconds.
17.Measure the bubbles from the surface of the water to the top of the bubbles.
Test #3
1. Run tap water into a container (100ml.)
2. Run hard water to a separate container (100ml.)
3. Run RO water to a third container (100ml.)
4. Put one drop (.25ml) of liquid soap into each container of water.
5. Put a cap on each container.
6. Shake each bottle for a few seconds.
7. Measure from the surface of the water to the top of the bubbles.

 
 


BACK GROUND REPORT


 






In the next few pages I will be telling you bout three different kinds of water. I will be including how water becomes hard and the effects of hard water. I will also be talking about the process of how water is softened and its great advantages. Finally I will be talking about Reverse Osmosis Water and its advantages and disadvantages. 

Hard Water

Hard water contains dissolved calcium and magnesium ions. Commonly called “hardness minerals,” dissolved calcium and magnesium can cause many problems when present in a water supply. When it’s from a well or municipal water utility, water usually contains these elements. When water has fallen from the sky in it’s different forms, it absorbs carbon dioxide in the air and becomes slightly acidic. The water then reaches and enters the ground and because it is acidic it absorbs calcium magnesium, among other things, from layers of rock that it passes through. Minerals neutralize the water’s acidity but also make it hard. Then the water finds bigger bodies of water (either above or below the ground) and eventually ends up in your home.

Water hardness is usually measured in “grains per gallon,” an indication of the amount of dissolved magnesium and calcium the water contains. With as little as one grain per gallon is classified as “hard” to certain extent.

Hard water usually causes soap scum in the tub and shower, and hard water spots on faucets and fixtures. According to Ohio State University study, that the average person with hard water spends more than six hours a month on cleaning tap water spots, streaks and scum alone.

Hardness minerals react with soaps and detergents, which forms an insoluble, sticky residue that is very difficult to remove from bathtubs, sinks, faucets and fixtures. That exact same soap is often left on hair, skin and clothing which causes rashes, your skin to dry and itch, and clothing to fade and wear prematurely. 

Hard water can cause plants to suffer. When you water them with hard water sometimes the water has certain minerals that are not good for the plants. There have been cases in which the water contained so much iron that it has turned grass orange-red, and some cases were the iron has turned inside appliances the same color. 

Hard water causes other problems as well. After a while scale formed from continuous contact with dissolved minerals in water can collect inside plumbing and on the internal parts of water-using appliances. Hard water scale can also coat the inside of a water heater and drastically reduce its heating ability. 

So basically hard water is a poor choice of water. The only possible good use of hard water is that it has good flow rates. Although it has good flow rates it doesn’t even come close to comparing against its negative results in the long run, or sometimes the short run. Soap scum builds, ruins house equipment and is unhealthy. Hard water is definitely not a good water source. 

Softened Water

Softened water is mainly free of all dissolved calcium or magnesium. There is a small amount of houses that have naturally softened water. A huge percentage of homes with soft water are equipped with bought products known as Water Softeners. 

The most common process of softening water is ion exchange. First the water enters the water softener. Then it comes in contact with a bed of tiny beads that contain sodium chloride or potassium chloride ions. The beads are chemically attracted to calcium and magnesium ions and as a result ion exchange occurs. After that the calcium and magnesium ions “stick” to the surface of the beads, which dislodges the sodium or potassium. When the beads are completely exhausted (covered with calcium and magnesium), a solution is brought to the system to wash away the calcium and magnesium. Then it replaces the sodium or potassium (a process that is known as regeneration). After the extra solution has been rinsed from the risen bed, the entire ion exchange cycle begins again. 

Most water supplies contain different kinds of minerals. So as a result softeners can be designed to help with other water problems. Some examples of what softeners do are that they reduce radium, manganese and excess iron. 
There are several advantages to having soft water. The biggest advantage is that it reduces the amount of minerals in your water. Another advantage to having soft water is that it can dramatically reduce soap usage. The water is already soft so the cleaning agents don’t have hard minerals to react with and over come, so the soap works more efficiently. Most of the ingredients in most soaps and detergents have chemical “water softeners” that are added to prevent the reaction between the detergent and hardness
minerals present in most water (the reaction that causes it to form a sticky residue or soap curd). As a result of chemicals that are not necessary for cleaning with soft water, less soap is needed. Soft Water households save money on laundry soap, shampoo and other cleaning products. 
Soft Water doesn’t contain scale-forming minerals; it leaves the inside of plumbing and water using appliances free of solidified rock. Appliances operate more efficiently and last longer with the use of Soft Water. 

Reverse Osmosis 

Reverse Osmosis is the most economical method of removing 90%-99% of all contaminants. The RO membrane’s pore structure is much tighter than Uf membranes. RO membranes can reject almost all particles, bacteria and organic 300 Dalton macular weight (including pyrogens). 

Ro involves an ionic exclusion process. Only solvent is allowed through the semi-permeable Ro membrane, while all ions and dissolved molecules are retained (including salts and sugars). The semi-permeable membrane rejects all salts (ions) by a charge phenomena action: the greater the charge, the greater the rejection. So as a result the membrane rejects nearly all (99%) strongly ionized polyvalent ions but only 95% of the weakly ionized monovalent ions like sodium. 

Osmosis occurs when a semi- permeable membrane separates solutions that have two different concentrations. The osmotic pressure drives water through the membrane; the water dilutes the more concentrated solution; and the end result is equilibrium. While in the purification system hydraulic pressure is applied to the concentrated solution to counteract the osmotic pressure. Pure water is driven from the concentrated solution and collects downstream of the membrane.

Different feed of water may require different types of RO membranes. Membranes are manufactured from cellulose acetate or thin- film composites of polyamide on a polysulfone substrate.RO membranes are very restrictive; they yield very slow flow rates. Strong tanks are required to produce an adequate volume in a reasonable amount of time. 

There are several advantages of Reverse Osmosis. The number one advantage is that it effectively removes almost all types of contaminants (particles, pyrogens, microorganisms, colloids and dissolved inorganics).

The only disadvantage of RO water is that it has limited flow rates. So as you can see having RO water is not a bad idea because the only problem is slow flow rates but that isn’t a big factor compared to its advantages.

This project can benefit you and generations to come because if we are all aware of what water supply we have, it can help us with health issues and save money on appliances and soaps etc. This report was written to let you know about these three different types of water, their advantages and disadvantages.
 


RESULTS


 

Test #1

What I wanted to learn from this experiment is how much conductivity each water type has. Each water type had at least a little bit of conductivity. The RO water had a very small amount of parts per million (conductivity). The Softened water had more parts per million but not even close to the amounts of the hard water. The hard water had the most amount of conductivity. 

Test #2

By doing this experiment I was hoping to learn what kind of water between RO water, hard water and soft water would work the best to rinse out soap. During this experiment all three of the pieces of cloth had soap that was not completely rinsed out. Each time I did this experiment with the RO water there was a result of about 4 mm high of soap, while soft water had about 5 mm and hard water had about 8 mm of bubbles. 

Test #3

What I wanted to learn from this experiment is how soap interacts with each water type. The soap didn’t even have an effect on the hard water. After shaking the bottle with hard water and soap no suds had formed. The soft water formed quite a few suds while the RO water formed about twice as many as the soft water.
Test #1

 
Water Type
Parts per Million
PPM
PPM
PPM
PPM
PPM
Average

In PPm

RO Water
40
52
50
50
49
51
48.6
Soft

Water

257
263
268
264
264
267
263.83
Hard Water
256
259
253
253
254
254
254.83


Test #2

Water Type

Millimeter

Mm
Mm
Mm
Mm

Average

In Mm
RO Water
4
5.5
3
4
4.5
4
Soft Water
5
4.5
5.5
5
5
5
Hard Water
7.5
8
7.5
6.5
7
7.3


Test #3

Water Type
Millimeters
Mm
Mm
Mm
Mm
Average

In Mm

RO Water
15
15.5
15
16
14.5
15.2
Soft Water
7
7
7.5
7
6.5
7
Hard Water
0
0
0
0
0
0



 
 


ANALYSIS AND CONCLUSIONS


 


What we can learn from my results is that Reverse Osmosis water is the best choice for usage. The RO water had the least amount of conductivity was found in this water, soap interacted well with RO water and the RO water rinsed out the most soap in the cloths. Soft water is the second best choice out of these three for every experiment but the soft water does contain more conductivity than the other two. Finally that hard water is a poor choice. This water is unhealthy, does not interact with soap well and it does the worse job at rinsing out soap in fabric materials. 

Test #1
My hypothesis is that hard water will contain more metal parts per million. Secondly softened water will have some but not tremendous amounts of metal. RO water will have a very low count of metal parts per million. I arrived at this hypothesis because I found that hard water contains a lot of minerals. I have also found that softeners are used to reduce great amounts of minerals. Finally I found that Reverse Osmosis reduces about 99% of the minerals that the water contains. 

Test #2
My hypothesis is that the hard water will have quite a few suds, I think that the bubbles will be at an average of about 5 millimeters.  The softened water will have a very small amount of soap left. The softened water will have about a millimeter of soap. Finally I don’t think there will be any soap with the RO water. I have arrived at this hypothesis because I have read that hard water does not rinse out very much of the soap that it has been washed in. Instead of rinsing the soap out it causes it to form a paste and it sticks to the cloth. I have also read that soft water has a reduced amount of minerals so as a result the paste will not form and sick to the cloth. The RO water has almost 99% of the minerals removed so it won’t make even the slightest bit of paste, so the soap will not stick to the cloth. 

Test #3
My hypothesis for this experiment is that RO water will have the most amount of bubbles from one drop of soap, while softened water will have the second highest amounts of bubbles and hard water will have very few bubbles if any at all. I have come to this hypothesis from the research I did that involved soap. When the fats in the soap mixes with the minerals in the water precipitation occurs. When the calcium and magnesium ions form insoluble salts with the fat in the soap, a curd-like precipitate occurs and settle. So as a result the soap is mixed with the water minerals and is not able to make bubbles like it is supposed to. The hard water has the most amount of minerals so it should not have very many bubbles, while the softened water has very little amounts of minerals, so it is aloud to form more bubbles. The RO water should have the most amount of bubbles because 99% of the minerals have been taken out so the soap doesn’t have to compete with as many minerals as the other two. 
Test #1
For my first test I accepted and rejected my hypothesis. My first hypothesis was accepted because RO water contained the least amount of metal. My hypothesis was also rejected because the soft water had more metal parts per million than the hard water. The reason why the soft water contained more metal is because the potassium does not do much to the hard minerals; you have to use more potassium than the minerals that the water already contained to get rid of most the minerals. 

Test #2
My second test I had rejected it. My test was rejected because the hard water had an average of 7.3 instead of 5. The soft water had an average of 5 and finally the RO water did have suds, it had an average of 4. 

Test #3
The third test I took I accepted and rejected my hypothesis. My hypothesis was accepted because the RO water had the most amount of bubbles and Soft water had the second highest amount of soap. It was rejected because there was not bubbles what so ever.

 


Questions


 


Test #1 


Test #2 
Test #3 
ERROR
Test #1  Test #2  Test #3 
BIBLIOGRAPHY

Gilfond, Henry, Water A Scarce Resource, New York, Franklin Watts,1978. 

Heindl, L.A., The Water We Live By, Canada, Lon Mans Canada Limited.

1970

Premium Drinking Water Micro Structed; Costco Whole Sale Corporation; Seattle, WA

P://www.flagcitywater.com/helpful_info_hard.html#recognize

Servicemagic.com

Sowry, Jo, Water, Great Britain, Prior Press Limited, 1979.

//www.nutrition.cornell.edu/nutriquest/04/799/fewater.html
 


APPENDIX


What is hard water? 

Hard water is water that contains dissolved minerals from rock, mainly calcium, magnesium and manganese. 

What is soft water? 

Soft water is basically water that is free of calcium, manganese and magnesium. 

What is Reverse Osmosis water?

RO water is water that has been treated through the process of Reverse Osmosis. 

Glossary

Calcium- a silver-white divalent metal
Ion- an electrically charged atom or group of atoms formed by the loss or gain of one or more electrons 
Ionize- to separate or change into ions 
Magnesium- a light, ductile, silver-white metallic element 
Manganese- a hard, brittle, grayish-white, metallic element
Potassium- a silver-white metallic element 
Sodium- a soft, silver-white, metallic element